En esta url pueden encontrar mas info!
http://lab.msdn.microsoft.com/express/beginner/default.aspx

Aquí un extracto..
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Absolute Beginner's Video Series to Visual Studio 2005 Express Editions

This video series is designed specifically for individuals who are interested in learning the basics of how to create applications using Visual Basic 2005 Express Edition and Visual C# 2005 Express Edition. This includes over 10 hours of video-based instruction that walks from creating your first "Hello World" application to a fully functioning RSS Reader application. Learn how to write your first application today!!

For more information on software development with Visual Basic Express Edition or Visual C# Express Edition, you may be interested in these Supplemental Readings (Requires Adobe Acrobat Reader)

Lessons

Lesson 1: Getting Started with Visual Studio 2005 Express Editions

This lesson provides an overview of the 16 lesson series, walks through the completed RSS Reader project and shows how to create your first "Hello World" application.

Duration: 24 minutes, 26 seconds
Video: Visual Basic | Visual C#
Projects: Visual Basic | Visual C#

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Lesson 2: Creating a Windows Application User Interface

This lessons walks through using the basics of the Visual Studio IDE including the Toolbox and Properties Window in conjunction with controls like the button, label, MenuStrip, StatusStrip, and ToolStrip controls.

Duration: 43 minutes, 11 seconds
Watch: Visual Basic | Visual C#
Download: Visual Basic | Visual C#

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Lesson 3: Writing Code to Handle Events and Set Properties
This lesson explains what an event handler is and how you can write code to react to events and how to set properties for controls. You'll also learn how to use IntelliSense, add comments to your code, and use code regions.

Duration: 24 minutes, 44 seconds
Watch: Visual Basic | Visual C#
Download: Visual Basic | Visual C#

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Lesson 4: Working with Variables, Expressions, Statements, and Operators
This lesson explains what a variable is and how to use them in your applications. You’ll also learn the difference between expressions and statements and how you can use operators, like the addition operator (+) in your code.

Duration: 29 minutes, 55 seconds
Video: Visual Basic | Visual C#
Projects: Visual Basic Project | Visual C#

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Saludos!

PD: por siaca, son mas lecciones...asi que vayan entrando!!!